Sync gome folders 2 nas

Hi Will Apprecaite your forum alot. I have 2 NAS drive, Syncing everything VIA Sync Drive Share Sync… very nice to have 2 running as if one go down, I just switch to the other… My Question… WAT IS YOUR opinion… Can I also Sync my home folder?? Run Synology photos on both. My users are the same on both Servers. Will everything happen As I think?? If you know what I mean?